A new three-dimensional analysis of the Sun’s ultraviolet spectrum has sharply reduced a long-standing disagreement between solar measurements and ancient meteorites, demonstrating that the apparent shortage originated largely within the models used to interpret sunlight.
For years, astronomers faced a persistent chemical discrepancy involving the Sun and some of the oldest surviving material in the Solar System. Measurements of the solar photosphere—the visible atmospheric layer from which most sunlight escapes—indicated that the Sun contained substantially less silver than scientists expected to find.
That result was difficult to reconcile with measurements from CI carbonaceous chondrites, an exceptionally primitive class of meteorites containing material associated with the formation of the Solar System approximately 4.6 billion years ago. For many elements, the chemical composition recorded in these meteorites closely corresponds with the composition inferred from the Sun.
Silver refused to match.
The Sun’s measured silver abundance was approximately 0.25 dex below the meteoritic value. In astronomical abundance measurements, dex represents a logarithmic difference rather than an ordinary percentage. A separation of 0.25 dex means the meteoritic estimate was nearly 1.8 times the previously accepted solar value.
The disagreement raised a fundamental question. If the Sun and CI chondrites developed from the same early reservoir of gas and dust, why did the Sun appear to contain so much less silver?
New research indicates that much of the discrepancy originated in the way astronomers interpreted silver’s spectral signature.
A team consisting of Sema Caliskan, Anish M. Amarsi, Per Jönsson, Nicolas Grevesse, and Bijaya K. Sahoo constructed the first comprehensive model of neutral silver designed for a three-dimensional, non-local-thermodynamic-equilibrium analysis of the solar atmosphere. Their results, published in Astronomy & Astrophysics, raised the recommended solar silver abundance by 0.19 dex—approximately 55 percent above the previous reference value.
The correction reduced the difference between the Sun and primitive meteorites from 0.25 dex to 0.06 dex.
The discovery did not involve retrieving physical silver from the Sun, detecting a previously unseen deposit, or observing silver flowing through the solar atmosphere. It resulted from a more accurate interpretation of sunlight.
READING THE SUN WITHOUT TOUCHING IT
Scientists cannot collect a physical sample from the Sun’s photosphere and return it to a terrestrial laboratory. They determine its chemical composition through spectroscopy—the study of how matter emits, absorbs, and modifies light.
As radiation moves through the solar atmosphere, atoms absorb energy at specific wavelengths. Each chemical element produces a distinct pattern of spectral lines governed by its atomic structure. These lines act as chemical fingerprints, allowing astronomers to identify elements and estimate their abundance from nearly 93 million miles away.
A spectral line does not provide an abundance automatically. Scientists must calculate how atoms behave inside a dynamic environment shaped by temperature, density, radiation, convection, ionization, and collisions.
If the physical model describing that environment is incomplete, the inferred abundance can also be incomplete.
Solar silver is particularly difficult to measure because astronomers depend primarily upon two resonance lines produced by neutral silver, designated Ag I, at approximately 328.1 and 338.3 nanometers. Both lines sit in the near-ultraviolet region of the spectrum, where surrounding spectral features can complicate measurements.
The two lines represent a narrow observational foundation for determining the abundance of an element with major importance to astrophysics. Errors in the atomic data, atmospheric model, line measurement, or treatment of radiation can alter the final result.
Earlier solar silver estimates used sophisticated three-dimensional atmospheric modeling, but they still assumed local thermodynamic equilibrium, commonly abbreviated as LTE.
The new study found that this assumption caused the solar silver abundance to be underestimated.
WHY LOCAL THERMODYNAMIC EQUILIBRIUM MATTERS
Local thermodynamic equilibrium assumes that conditions within a small region of a stellar atmosphere can be described primarily by the local temperature and density. Under that approximation, atomic excitation and ionization states follow predictable statistical distributions.
LTE simplifies an immensely complicated physical system. It works reasonably well for some elements and spectral lines under certain conditions. It is not universally accurate.
Radiation in the solar atmosphere can travel considerable distances before interacting with matter. An atom at one location may therefore be affected by radiation originating in another region with different physical conditions. The energy states of the atom may not correspond to what the immediate local temperature alone would predict.
That departure affects how strongly the atom absorbs light.
In the case of silver, the research team found that neutral silver atoms in the line-forming region were driven away from the distributions predicted under LTE. Radiation depleted the population of neutral silver atoms occupying the ground state associated with the two diagnostic lines. This weakened the observable absorption signatures.
A weaker spectral line can be interpreted as evidence that less silver is present. The new calculation demonstrated that the same weak lines could be produced by a greater silver abundance once the non-equilibrium behavior of the atoms was represented properly.
The recorded sunlight did not change. The physical interpretation of that light did.
BUILDING A SILVER ATOM INSIDE A COMPUTER
The research required far more than adjusting a single number. Caliskan and her colleagues constructed a detailed model atom for neutral silver using the best available radiative and collisional information.
The model included 57 fine-structure energy levels, with data drawn from the National Institute of Standards and Technology Atomic Spectra Database. The researchers supplemented the limited available oscillator-strength information with additional atomic calculations.
Oscillator strengths describe the probability that an atom will absorb or emit radiation during a transition between energy states. Accurate values are necessary for connecting an observed spectral line to the quantity of an element producing it.
The researchers also modeled collisions involving electrons and neutral hydrogen, excitation between atomic states, charge-transfer processes, photoionization, isotopic contributions, and hyperfine structure. Silver possesses two stable isotopes, silver-107 and silver-109, both of which contribute to its spectral signature.
The calculations were then combined with a three-dimensional radiation-hydrodynamic model of the solar atmosphere. Unlike a simplified one-dimensional atmosphere, the three-dimensional model represents variations associated with solar granulation, vertical structure, moving material, and temperature differences across the photosphere.
The team analyzed ten snapshots of the modeled solar atmosphere and calculated how the two silver lines would form under several physical treatments. These included one-dimensional and three-dimensional atmospheres, along with LTE and non-LTE conditions.
Under the complete three-dimensional non-LTE calculation, the researchers obtained a recommended logarithmic silver abundance of 1.15, with an uncertainty of plus or minus 0.08. The preceding reference value was 0.96.
Because the abundance scale is logarithmic, the 0.19-dex correction corresponds to an increase of approximately 55 percent.
WHY THE METEORITE COMPARISON MATTERS
CI carbonaceous chondrites preserve an important chemical record of primitive Solar System material. They are not physical pieces of the Sun or perfect copies of the solar photosphere. Their elemental composition provides one of the strongest available standards for reconstructing the non-gaseous material present when the Solar System formed.
The Sun and these meteorites developed from the same broad protoplanetary environment. Their elemental abundances should display close agreement after scientists account for the processes that can separate, deplete, or concentrate certain materials.
The revised solar abundance reduces the remaining silver difference to approximately 15 percent. That residual falls within the range of recent findings involving other moderately volatile elements and the uncertainties surrounding solar and meteoritic measurements.
The new result removes the need for an extraordinary explanation involving the selective loss of a large quantity of silver from the Sun. It indicates that the earlier disagreement arose primarily from limitations in the interpretation of the two ultraviolet lines.
SILVER IS MORE THAN A PRECIOUS METAL
On Earth, silver is associated with currency, jewelry, electronics, photography, medical applications, solar panels, conductive materials, and industrial manufacturing. In astrophysics, its importance extends far beyond its terrestrial uses or economic value.
Silver has atomic number 47 and belongs to a group of elements heavier than iron whose origins involve neutron-capture nucleosynthesis. Atomic nuclei can build heavier elements by capturing neutrons and undergoing radioactive transformations that convert neutrons into protons.
One major pathway is the rapid neutron-capture process, or r-process, in which atomic nuclei absorb neutrons faster than radioactive decay can stabilize them. Current models attribute close to 80 percent of the Solar System’s silver to r-process nucleosynthesis.
The exact cosmic environments responsible for producing all observed silver remain under investigation. Neutron-star mergers can create substantial quantities of heavy r-process elements. Certain supernova-related environments and other extreme stellar events may contribute to lighter neutron-capture elements through separate or overlapping pathways.
Silver is especially useful because it sits within an atomic-number region where lighter r-process elements do not always follow the abundance pattern observed among heavier r-process elements. Astronomers sometimes describe this behavior through a weak or limited r-process component distinct from the main r-process pattern.
Accurate silver measurements can help scientists determine whether multiple nucleosynthetic channels contributed to the elements now distributed throughout the Milky Way.
The Sun serves as an essential chemical reference point for those comparisons. An underestimated solar value can distort the baseline used to evaluate other stars. Correcting that baseline strengthens future investigations into the origin and galactic distribution of silver.
THE SUN IS THE BENCHMARK, NOT THE FINAL DESTINATION
The Sun served as the first benchmark for the new model because its spectrum, atmospheric properties, and elemental composition have been studied with exceptional precision. A model tested successfully against solar observations provides a stronger foundation for analyzing more distant stars.
The research team plans to apply the same three-dimensional non-LTE approach to metal-poor dwarf and giant stars. These ancient stellar populations preserve chemical information from earlier periods of galactic history, when fewer generations of stars had enriched the Milky Way with heavy elements.
Measurements of silver across stars of different ages, masses, and metallicities could reveal when silver entered the galaxy, how its abundance changed over time, and which stellar events supplied it.
Earlier surveys reported substantial star-to-star variation in silver abundance and a difference of roughly 0.5 dex between dwarf and giant stars at comparable metallicities. Some of that separation may represent genuine differences in galactic chemical history. Another portion may have originated in the LTE assumptions used to interpret the stellar spectra.
Applying the new model will allow researchers to distinguish more clearly between differences produced by stellar history and those created by the analytical method.
If the corrected measurements reduce the separation between dwarf and giant stars, the earlier models were responsible for part of the disagreement. If substantial differences remain, the surviving pattern could provide stronger evidence of the physical events that distributed silver across the galaxy.
WHY THE MYSTERY IS NOT COMPLETELY CLOSED
The study establishes a compelling explanation for most of the Sun’s apparent silver shortage, but it does not eliminate every scientific uncertainty.
The recommended abundance carries an uncertainty of plus or minus 0.08 dex. Sensitivity tests found that the result is most affected by the treatment of inelastic collisions between silver and neutral hydrogen. The ultraviolet lines also remain difficult to measure because they occupy a crowded region of the spectrum affected by neighboring atomic features.
The new value does not exactly equal the meteoritic measurement. A small residual difference remains, although it is consistent with current findings involving other moderately volatile elements.
These limitations do not undermine the central result. They define its scientific boundaries. The study substantially resolves the original discrepancy while identifying the areas where improved atomic data and additional observations could refine the measurement.
WHAT THE DISCOVERY REVEALS ABOUT ASTRONOMY
The Sun did not acquire additional silver when the calculations were completed. Humanity gained a more accurate method for determining how much silver had been present.
That distinction illustrates the relationship between observation and interpretation in astronomy.
A telescope records radiation. A spectrograph separates that radiation into measurable wavelengths. Neither instrument independently explains the physical processes that produced the signal. Researchers must connect the observations to reality through atomic data, mathematical calculations, atmospheric simulations, and physical assumptions.
Scientific models are not the objects they describe. They are tools used to interpret evidence that cannot always be examined directly.
The apparent silver shortage persisted because the two ultraviolet lines did not behave within the solar atmosphere exactly as the LTE approximation predicted. Once the researchers represented the three-dimensional atmosphere and the non-equilibrium behavior of silver atoms, the inferred abundance rose.
The finding demonstrates how a small number of spectral lines, interpreted through more complete atomic physics, can alter humanity’s understanding of the chemical history of the Solar System.
It also serves as a warning against treating every astronomical estimate as a direct inventory. Some values depend heavily upon the accuracy of the physical model standing between the signal and the conclusion.
TRJ VERDICT
The new solar silver measurement represents a significant advance in atomic physics, solar spectroscopy, and the study of galactic chemical evolution.
Sema Caliskan, Anish M. Amarsi, Per Jönsson, Nicolas Grevesse, and Bijaya K. Sahoo developed the first detailed three-dimensional non-LTE model of neutral silver and used it to explain most of a long-standing disagreement between the Sun and primitive meteorites.
The research does not settle every question concerning silver’s solar abundance or cosmic origin. It provides a far stronger measurement, sharply narrows the meteoritic discrepancy, and establishes a new foundation for studying silver in other stars.
The central lesson is clear: the Sun’s apparent shortage of silver was largely a shortage within the earlier model.
The light carried the evidence.
Science developed a better way to read it.
Sema Caliskan, Anish M. Amarsi, Per Jönsson, Nicolas Grevesse, and Bijaya K. Sahoo, “Ag I Model Atom and the 3D Non-LTE Solar Silver Abundance,” Astronomy & Astrophysics, Vol. 711, Article A155, 2026. (Free Download)
Sema Caliskan, Anish M. Amarsi, Per Jönsson, Nicolas Grevesse, and Bijaya K. Sahoo, “Ag I Model Atom and the 3D Non-LTE Solar Silver Abundance,” arXiv:2605.05356v1, May 2026. (Free Download)
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John, very interesting piece!
Aside: I read your poem in Spillwords about the last Apollo mission. Loved it! Don’t think I saw a post about it, perhaps I missed it, but I just happened upon it while reading SW. Great job! 😎👍🚀
Thank you very much, Darryl! I’m glad you enjoyed the article. We regularly come across exaggerated or misleading claims about fascinating subjects, and people often accept them because they make compelling clickbait. We are working to identify those claims and examine the underlying research so our readers receive the facts. We will continue covering these subjects whenever we find them.
It was a wonderful surprise to hear that you happened across my Apollo poem while reading Spillwords. We also posted it on TRJ, but I’m really glad you discovered it there and loved it. I appreciate you letting me know. It means a great deal.
Thank you again for reading, commenting, and continuing to support our work, Darryl. I hope you have a great weekend. 😎